Room temperature photoluminescence (PL) properties of vertically aligned and spindle-shaped, randomly oriented ZnO nanorods synthesized by using a low temperature hydrothermal method are studied. In air, the vertically aligned ZnO nanorods oriented mainly parallel to the luminescencerecording axis exhibited only one, very strong UV emission peak at 382 nm. This band is assigned to emission of free excitons. A new violet PL band near 400 nm arises with increasing angle between the nanorod growth direction and the luminescence-recording axis. The violet band also appears under UV illumination in vacuum and vanishes after exposure to air. The randomly oriented ZnO nanorods along with free exciton related PL band reveal a broad yellow-orange emission band around 590 nm. The violet band is attributed to Zn vacancy related defects or their complexes, while the yellow-orange emission band is ascribed to oxygen interstitial related defects.
| Mualliflar | Kurbanov, S.S., Urolov, Sh.Z., Shaymardanov, Z.Sh., Jalolov, R.R. |
|---|---|
| Jurnal | O‘zbekiston fizika jurnali |
| Nashr sanasi | 2018-07-21 |
| Jild | 20 |
| Son | 4 |
| Betlar | 209-217 |
| Til | Ingliz |
| DOI | 10.52304/.v20i4.94 |
DOI: 10.52304/.v20i4.94 · Maqolaning asl sahifasi
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