This paper investigates the thermodynamic principles of selective arsenic removal from iron oxide pigments obtained from technogenic solutions generated during the neutralization of bio-oxidation products. The temperature dependence of Gibbs free energy for reactions involving sodium sulfide was analyzed to evaluate the thermodynamic stability of iron- and arsenic-containing compounds. The calculations demonstrated that arsenic-bearing phases readily transform into sulfide compounds, whereas iron compounds remain thermodynamically stable. The optimal temperature range for selective arsenic removal was determined to be 40–60 °C. The obtained results provide a scientific basis for improving environmentally friendly technologies for processing bio-oxidation solutions and producing iron oxide pigments with reduced toxic impurity content.
| Mualliflar | Toshkodirova, Rano Erkinjonovna, Kenjayeva, Sevara Absamatovna, Тошкодирова, Рано Эркинжоновна, Кенжаева, Севара Абсаматовна, Toshqodirova, Rano Erkinjonovna, Kenjayeva, Sevara Absamatovna |
|---|---|
| Jurnal | Саноатда рақамли технологиялар |
| Nashr sanasi | 2026-06-29 |
| Jild | 4 |
| Son | 2 |
| Betlar | 74-80 |
| Til | Rus |
| DOI | 10.70769/3030-3214.srt.4.2.2026.28 |
DOI: 10.70769/3030-3214.srt.4.2.2026.28 · Maqolaning asl sahifasi
bio-oxidation, technogenic solution, iron oxide pigment, arsenic, sodium sulfide, Gibbs free energy, thermodynamic analysis, selective purification, environmental safety, metallurgical waste, биоокисление, техногенный раствор, железооксидный пигмент, мышьяк, сульфид натрия, энергия Гиббса, термодинамический анализ, селективная очистка, экологическая безопасность, металлургические отходы, biooksidlanish, texnogen eritma, temir oksidli pigment, mishyak, natriy sulfidi, Gibbs erkin energiyasi, termodinamik tahlil, selektiv tozalash, ekologik xavfsizlik, metallurgiya chiqindilari
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