The oxadiazole derivatives complex compounds with metals are biologically active substances. The aim of the study was to study the interaction of the chlorides of Co (II), Ni (II), Cu (II) and Mn (II) with 5-(4-pyridyl)-1,3,4-oxadiazole-2(3H)–thione, ammonium vanadate. Competitive coordination of donor centers, electronic and geometric structures of the ligand molecule were studied on the basis of the quantum-chemical software package Gaussian09 LanL2DZ. It was shown that 5-(4-pyridyl)-1,3,4-oxadiazole-2(3H)-thione ligand is partially coordinated through a localized nitrogen or sulfur atoms at formation of the complex. А procedure was developed for the synthesis of new mixed-metal complexes. The composition and structure of the synthesized compounds were studied using elemental analysis, termogravimetric and X-ray phase analysis and IR spectroscopy.
| Mualliflar | Mehribon, PIRIMOVA, Shakhnoza, KADIROVA, Dilnoza, RAKHMONОVA, Abduhakim, ZIYAYEV |
|---|---|
| Jurnal | Kimyo va kimyo texnologiyasi |
| Nashriyot | Тошкент кимё-технология институти |
| ISSN | 1992-9498, 2181-1121 |
| Nashr sanasi | 2020-06-20 |
| Betlar | 43-47 |
| Til | Ingliz |
| Ilmiy soha | Kimyo |
| DOI | 10.51348/zrqh4631 |
| Indeksga qo‘shilgan | 2026-09-02 |
DOI: 10.51348/zrqh4631 · Maqolaning asl sahifasi
| APA | Mehribon, PIRIMOVA, Shakhnoza, KADIROVA, Dilnoza, RAKHMONОVA, & Abduhakim, ZIYAYEV (2020). SYNTHESIS AND RESEARCH OF NEW HETEROMETAL COMPLEXES Cо(II), Ni(II), Cu(II) AND Mn(II) BASED ON V(V) AND 5-(4-PYRIDYL)-1,3,4-OXADIAZOLE-2(3H)-THIONE LUBRICANTS. Kimyo va kimyo texnologiyasi, 43-47. https://doi.org/10.51348/zrqh4631 |
|---|---|
| GOST (OAK) | Mehribon, PIRIMOVA va b. SYNTHESIS AND RESEARCH OF NEW HETEROMETAL COMPLEXES Cо(II), Ni(II), Cu(II) AND Mn(II) BASED ON V(V) AND 5-(4-PYRIDYL)-1,3,4-OXADIAZOLE-2(3H)-THIONE LUBRICANTS // Kimyo va kimyo texnologiyasi. – 2020. – P. 43-47. – DOI: 10.51348/zrqh4631. |
| MLA | Mehribon, PIRIMOVA, Shakhnoza, KADIROVA, Dilnoza, RAKHMONОVA, and Abduhakim, ZIYAYEV. “SYNTHESIS AND RESEARCH OF NEW HETEROMETAL COMPLEXES Cо(II), Ni(II), Cu(II) AND Mn(II) BASED ON V(V) AND 5-(4-PYRIDYL)-1,3,4-OXADIAZOLE-2(3H)-THIONE LUBRICANTS.” Kimyo va kimyo texnologiyasi, 43-47, 2020. https://doi.org/10.51348/zrqh4631 |
| Chicago | Mehribon, PIRIMOVA, Shakhnoza, KADIROVA, Dilnoza, RAKHMONОVA, and Abduhakim, ZIYAYEV. “SYNTHESIS AND RESEARCH OF NEW HETEROMETAL COMPLEXES Cо(II), Ni(II), Cu(II) AND Mn(II) BASED ON V(V) AND 5-(4-PYRIDYL)-1,3,4-OXADIAZOLE-2(3H)-THIONE LUBRICANTS.” Kimyo va kimyo texnologiyasi, 43-47 (2020). https://doi.org/10.51348/zrqh4631 |
| Harvard | Mehribon, PIRIMOVA, Shakhnoza, KADIROVA, Dilnoza, RAKHMONОVA, and Abduhakim, ZIYAYEV (2020) ‘SYNTHESIS AND RESEARCH OF NEW HETEROMETAL COMPLEXES Cо(II), Ni(II), Cu(II) AND Mn(II) BASED ON V(V) AND 5-(4-PYRIDYL)-1,3,4-OXADIAZOLE-2(3H)-THIONE LUBRICANTS’, Kimyo va kimyo texnologiyasi, 43-47. https://doi.org/10.51348/zrqh4631 |
| BibTeX | @article{mehribonpirimova2020,
title = {SYNTHESIS AND RESEARCH OF NEW HETEROMETAL COMPLEXES Cо(II), Ni(II), Cu(II) AND Mn(II) BASED ON V(V) AND 5-(4-PYRIDYL)-1,3,4-OXADIAZOLE-2(3H)-THIONE LUBRICANTS},
author = {Mehribon, PIRIMOVA and Shakhnoza, KADIROVA and Dilnoza, RAKHMONОVA and Abduhakim, ZIYAYEV},
journal = {Kimyo va kimyo texnologiyasi},
year = {2020},
pages = {43-47},
doi = {10.51348/zrqh4631},
url = {https://doi.org/10.51348/zrqh4631}
} |
Boshqa maqola uchun iqtibos tayyorlash
With the aim of determination of electronic and geometrical structures of mixed-ligand complexes, theoretical modeling of the structures of coordination compounds of transition metals with dialkyldithiophosphate…
The synthesis of mixed ligand coordination compounds of copper, cobalt and nickel formates with formamide and urea in an aqueous solution was carried out. The metal content in the complexes was determined by…
Considering the protein need for human nutrition, the use of protein-rich grains plays an important role in the production of pasta. The study used soy protein as one of the protein sources, which serves as an effective…
The process of formation of supramolecular complexes of glycyrrhizinic acid with some phytohormones (indolylacetic acid, indolylbutyric acid, α-naphthyl acetic acid and kinetin) were studied with the aim of creation the…
The aim of the study was to study the conditions of copolycondensation of phenol alcohol with hydroxyl-containing polyether polyol in the presence of maleic anhydride chain extender in order to obtain modified thermoset…
The paper analyzes the available resources for the creation of a cluster approach to the integration of education, science and industry in order to create a mechanism to bring the development of the economy to the level…
The aim of the research work elaboration of technology of obtaine of acetylene diols and their vinyl ethers. Reaction of formation mono di vinyl ethers as a result vinyl 3,6-dimetyloktin-4-diol-3,6 by acetylene, and…
The purpose of this research is to study the possibilities of modeling oil-water emulsion in the laboratory. The study of the ratio of components and conditions of dispersion (formation) of oil-water emulsions on their…
Attention to 2-allylphenol (2-AF) and its synthesis is due by the fact that this compound is the starting material for the production of a number of biologically active natural compounds, such as synthetic fungicide. A…
For the first time, the amino acid composition of the buffer of soluble proteins of the Artemia cyst of the Aral Sea was determined. The determination of the qualitative and quantitative amino acid content of the buffer…
Kimyo va kimyo texnologiyasi — barcha maqolalar · 2020-yil arxivi
Ushbu maqolada ingliz tilini xorijiy til sifatida o‘rganishda yangi so‘zlarni vizual va verbal usullar orqali o‘zlashtirish samaradorligi tahlil qilinadi. Tadqiqotda vizual materiallar (rasmlar, grafik tasvirlar va…
Ushbu maqolada mashina tarjimasi (MT) vositalarining Toshkent Kimyo xalqaro universitetida tahsil olayotgan o‘zbek-ingliz ikki tilli talabalarning ingliz tilidagi yozma ishlarida uchraydigan xatolarga ta’siri…
Maqolada 1892-yilda “Туркестанские ведомости” gazetasida chop etilgan Sattorxon Abdulg'afforovning “Qo'qon xonligining ruslar tomonidan istilo etilishidan oldingi ichki ahvoli haqida qisqacha ocherk” asarining…
This article examines the linguistic units and metaphorical fields that structure English ecological discourse — the texts that construct public understanding of nature and environmental crisis. Drawing on Conceptual…
Maqolada 1929–1930-yillardan boshlab O‘zbekiston SSRda amalga oshirilgan yalpi kollektivlashtirish, “quloqlarni sinf sifatida tugatish” siyosati va majburiy surgunning mahalliy jamiyat hayotiga ta’siri Farg‘ona vodiysi…
Amudaryo quyi oqimidagi sugʻoriladigan hududlarda qishloq xoʻjaligi qurgʻoqchiligini asosan yogʻin emas, balki daryodan olinadigan suv hajmi belgilaydi. Tadqiqotda Xorazm viloyatida bir yillik (2000, 2008, 2011) va…