Influence of nanostructural catalyst in the synthesis of allyl phenyl ether and of its isomerization products

MUSAEV Khusniddin, Azimova Gulmira, TAJIMUKHAMMEDOV Khabibulla, Yuldashevа Mukhabbat

Kimyo va kimyo texnologiyasi · 2020-yil

Annotatsiya

Attention to 2-allylphenol (2-AF) and its synthesis is due by the fact that this compound is the starting material for the production of a number of biologically active natural compounds, such as synthetic fungicide. A number of recent publications have shown the high activity of zeolite, rhodium, iridium, and ruthenium catalysts in allylation reactions. The lack of these catalysts is their high cost. Therefore, the use of new effective and inexpensive catalysts in the reactions of synthesis and isomerization of allyl phenyl ether is important problem. The aim of this work is the selective synthesis of o-allylphenols in the isomerization of allyl phenyl ether under mild conditions using nanostructured catalysts. The methodology of the work is in finding new available and effective catalysts for the synthesis and targeted isomerization of allyl phenyl ether. When using nanostructured catalysts in the reaction of isomerization of allyl phenyl ether, using a mass chromatography method, it was found that the products of isomerization of allyl phenyl ether for one hour at a temperature of 90-95 °C are: (56%) 2-allylphenol; (2%) p-allylphenol, (12%) allyl-o-allyl phenyl ether, (4%) allyl-p-allyl-phenyl ether, and (26%) unisomerized allyl phenyl ether. For the first time the possibility of using small amounts of nanostructured catalyst Fe/SiO2·TiO2 in the synthesis of allyl phenyl ether and of its isomerisation products has been shown.

Maqola ma’lumotlari
MualliflarMUSAEV Khusniddin, Azimova Gulmira, TAJIMUKHAMMEDOV Khabibulla, Yuldashevа Mukhabbat
JurnalKimyo va kimyo texnologiyasi
NashriyotТошкент кимё-технология институти
ISSN1992-9498, 2181-1121
Nashr sanasi2020-01-12
Jild2019
Son4
TilIngliz
Ilmiy sohaKimyo
DOI10.70189/1992-9498.1144
Indeksga qo‘shilgan2026-09-02

DOI: 10.70189/1992-9498.1144 · Maqolaning asl sahifasi

Ilmiy soha

Kimyo

Iqtibos keltirish

APAMUSAEV Khusniddin, Azimova Gulmira, TAJIMUKHAMMEDOV Khabibulla, & Yuldashevа Mukhabbat (2020). Influence of nanostructural catalyst in the synthesis of allyl phenyl ether and of its isomerization products. Kimyo va kimyo texnologiyasi, 2019(4). https://doi.org/10.70189/1992-9498.1144
GOST (OAK)MUSAEV Khusniddin va b. Influence of nanostructural catalyst in the synthesis of allyl phenyl ether and of its isomerization products // Kimyo va kimyo texnologiyasi. – 2020. – T. 2019, № 4. – DOI: 10.70189/1992-9498.1144.
MLAMUSAEV Khusniddin, Azimova Gulmira, TAJIMUKHAMMEDOV Khabibulla, and Yuldashevа Mukhabbat. “Influence of nanostructural catalyst in the synthesis of allyl phenyl ether and of its isomerization products.” Kimyo va kimyo texnologiyasi, 2019(4), 2020. https://doi.org/10.70189/1992-9498.1144
ChicagoMUSAEV Khusniddin, Azimova Gulmira, TAJIMUKHAMMEDOV Khabibulla, and Yuldashevа Mukhabbat. “Influence of nanostructural catalyst in the synthesis of allyl phenyl ether and of its isomerization products.” Kimyo va kimyo texnologiyasi, 2019(4) (2020). https://doi.org/10.70189/1992-9498.1144
HarvardMUSAEV Khusniddin, Azimova Gulmira, TAJIMUKHAMMEDOV Khabibulla, and Yuldashevа Mukhabbat (2020) ‘Influence of nanostructural catalyst in the synthesis of allyl phenyl ether and of its isomerization products’, Kimyo va kimyo texnologiyasi, 2019(4). https://doi.org/10.70189/1992-9498.1144
BibTeX
@article{musaevkhusniddin2020,
  title = {Influence of nanostructural catalyst in the synthesis of allyl phenyl ether and of its isomerization products},
  author = {MUSAEV Khusniddin and Azimova Gulmira and TAJIMUKHAMMEDOV Khabibulla and Yuldashevа Mukhabbat},
  journal = {Kimyo va kimyo texnologiyasi},
  year = {2020},
  volume = {2019},
  number = {4},
  doi = {10.70189/1992-9498.1144},
  url = {https://doi.org/10.70189/1992-9498.1144}
}

Boshqa maqola uchun iqtibos tayyorlash

Kimyo va kimyo texnologiyasi jurnalidan boshqa maqolalar

Kimyo va kimyo texnologiyasi — barcha maqolalar · 2020-yil arxivi

Kimyo sohasidagi boshqa maqolalar

Kimyo sohasidagi OAK jurnallari