Review of 5-HMF synthesis: catalysis and technologies

Sitmuratov, Tulkinbek Sabirbayevich, Rakhmatullina, Alevtina Petrovnas, Ситмуратов, Тулкинбек Сабирбаевич, Рахматуллина, Алевтина Петровна, Sitmuratov, Tulkinbek Sabirbayevich, Rakhmatullina, Alevtina Petrovnas

Саноатда рақамли технологиялар · 2025-yil

Annotatsiya

5-Hydroxymethylfurfural (5-HMF) is recognized as a key platform molecule in the bioeconomy, serving as a precursor for the production of biofuels (2,5-dimethylfuran, 5-ethoxymethylfurfuryl ether), biopolymers (2,5-furandicarboxylic acid), and pharmaceutical intermediates. This review systematizes modern approaches to the synthesis of 5-HMF from carbohydrate feedstocks of varying complexity – from monosaccharides (fructose, glucose) to cellulose and lignocellulosic biomass (rice straw). Catalytic systems (homogeneous acids, ionic liquids, heterogeneous catalysts, including functionalized silica gel SiO₂-Imi-SO₃H and sulfated zeolite HSO₃-ZSM-5), solvent effects (dimethyl sulfoxide, biphasic water/organic solvent systems, including dichloromethane/tetrahydrofuran), process intensification methods (ultrasound, microwaves), and strategies for suppressing side reactions are analyzed in detail. The main pathways of 5-HMF chemical transformation are discussed, along with techno-economic and environmental aspects of production based on life cycle assessment (LCA) and bibliometric analysis. Key challenges (catalyst and separation costs, stability) and promising research directions (low-cost bifunctional catalysts, deep eutectic solvents, process integration, electrochemical methods, use of non-food biomass) are identified.

Maqola ma’lumotlari
MualliflarSitmuratov, Tulkinbek Sabirbayevich, Rakhmatullina, Alevtina Petrovnas, Ситмуратов, Тулкинбек Сабирбаевич, Рахматуллина, Алевтина Петровна, Sitmuratov, Tulkinbek Sabirbayevich, Rakhmatullina, Alevtina Petrovnas
JurnalСаноатда рақамли технологиялар
NashriyotҚарши муҳандислик-иқтисодиёт институти
ISSN3030-3214, 2023-2026
Nashr sanasi2025-11-08
Jild3
Son4
Betlar211-222
TilIngliz
Ilmiy sohaKimyo
DOI10.70769/3030-3214.srt.3.4.2025.10
Indeksga qo‘shilgan2026-08-26

DOI: 10.70769/3030-3214.srt.3.4.2025.10 · Maqolaning asl sahifasi

Kalit so‘zlar

5-hydroxymethylfurfural (5-HMF), biomass, carbohydrate dehydration, fructose, glucose, cellulose, ionic liquids, heterogeneous catalysts, biphasic systems, platform molecules, renewable feedstocks, biofuels, furandicarboxylic acid (FDCA), 5-гидроксиметилфурфурол (5-ГМФ), биомасса, дегидратация углеводов, фруктоза, глюкоза, целлюлоза, ионные жидкости, гетерогенные катализаторы, двухфазные системы, платформенные молекулы, возобновляемые сырьевые материалы, биотопливо, фурандикарбоновая кислота (ФДКА), 5-gidroksimetilfurfurol (5-GMF), biomassa, uglevodlar degidratatsiyasi, fruktoza, glyukoza, sellyuloza, ion suyuqliklar, geterogen katalizatorlar, ikki fazali tizimlar, platforma molekulalari, qayta tiklanadigan xomashyolar, bioyoqilg‘ilar, furankarbon kislotasi (FDKK)

Ilmiy soha

Kimyo

Iqtibos keltirish

APASitmuratov, Tulkinbek Sabirbayevich, Rakhmatullina, Alevtina Petrovnas, Ситмуратов, Тулкинбек Сабирбаевич, Рахматуллина, Алевтина Петровна, Sitmuratov, Tulkinbek Sabirbayevich, & Rakhmatullina, Alevtina Petrovnas (2025). REVIEW OF 5-HMF SYNTHESIS: CATALYSIS AND TECHNOLOGIES. Саноатда рақамли технологиялар, 3(4), 211-222. https://doi.org/10.70769/3030-3214.srt.3.4.2025.10
GOST (OAK)Sitmuratov, Tulkinbek Sabirbayevich va b. REVIEW OF 5-HMF SYNTHESIS: CATALYSIS AND TECHNOLOGIES // Саноатда рақамли технологиялар. – 2025. – T. 3, № 4. – P. 211-222. – DOI: 10.70769/3030-3214.srt.3.4.2025.10.
MLASitmuratov, Tulkinbek Sabirbayevich, Rakhmatullina, Alevtina Petrovnas, Ситмуратов, Тулкинбек Сабирбаевич, Рахматуллина, Алевтина Петровна, Sitmuratov, Tulkinbek Sabirbayevich, and Rakhmatullina, Alevtina Petrovnas. “REVIEW OF 5-HMF SYNTHESIS: CATALYSIS AND TECHNOLOGIES.” Саноатда рақамли технологиялар, 3(4), 211-222, 2025. https://doi.org/10.70769/3030-3214.srt.3.4.2025.10
ChicagoSitmuratov, Tulkinbek Sabirbayevich, Rakhmatullina, Alevtina Petrovnas, Ситмуратов, Тулкинбек Сабирбаевич, Рахматуллина, Алевтина Петровна, Sitmuratov, Tulkinbek Sabirbayevich, and Rakhmatullina, Alevtina Petrovnas. “REVIEW OF 5-HMF SYNTHESIS: CATALYSIS AND TECHNOLOGIES.” Саноатда рақамли технологиялар, 3(4), 211-222 (2025). https://doi.org/10.70769/3030-3214.srt.3.4.2025.10
HarvardSitmuratov, Tulkinbek Sabirbayevich, Rakhmatullina, Alevtina Petrovnas, Ситмуратов, Тулкинбек Сабирбаевич, Рахматуллина, Алевтина Петровна, Sitmuratov, Tulkinbek Sabirbayevich, and Rakhmatullina, Alevtina Petrovnas (2025) ‘REVIEW OF 5-HMF SYNTHESIS: CATALYSIS AND TECHNOLOGIES’, Саноатда рақамли технологиялар, 3(4), 211-222. https://doi.org/10.70769/3030-3214.srt.3.4.2025.10
BibTeX
@article{sitmuratovtulkinbeksabirbayevich2025,
  title = {REVIEW OF 5-HMF SYNTHESIS: CATALYSIS AND TECHNOLOGIES},
  author = {Sitmuratov, Tulkinbek Sabirbayevich and Rakhmatullina, Alevtina Petrovnas and Ситмуратов, Тулкинбек Сабирбаевич and Рахматуллина, Алевтина Петровна and Sitmuratov, Tulkinbek Sabirbayevich and Rakhmatullina, Alevtina Petrovnas},
  journal = {Саноатда рақамли технологиялар},
  year = {2025},
  volume = {3},
  number = {4},
  pages = {211-222},
  doi = {10.70769/3030-3214.srt.3.4.2025.10},
  url = {https://doi.org/10.70769/3030-3214.srt.3.4.2025.10}
}

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