Synthesis of internal acetylene alcohols based on the sonogashira reaction of terminal acetylene alcohols and benzolchloride

Guzal Otamukhamedova, Odiljon E. ZIYADULLAYEV, Abduvahob IKRAMOV, S.I Tirkasheva

Kimyo va kimyo texnologiyasi · 2024-yil

Annotatsiya

The purpose of the study is to develop a new catalytic system for the synthesis of internal acetylene alcohols from the Sonogastric coupling reaction of terminal acetylene alcohols and benzolchloride. For the first time in this work, internal acetylene alcohols have been synthesized based on reactions of some terminal acetylene alcohols – 3,4-dimethylpentin-1-ol-3, 3,4,4-trimethylpentin-1-ol-3, 1-ethynylcyclohexanol-1, 2-ethynyladamantanol-2, 2-phenylbutin-3-ol-2, 2-(naphthyl-2)butyn-3-ol-2, 2-(furanyl-2)butyn-3-ol-2 and 2-(pyridinyl-4)butyn-3-ol-2 with chloridebenzene. In order to achieve high product productivity in the Sonogashira reaction, alternative conditions have been identified by studying the molar ratios, spatial structure, induction effects of substituents, solvent and catalyst nature, as well as temperature, reaction duration effects, and the reaction mechanism has been proposed on the basis of literature sources.

Maqola ma’lumotlari
MualliflarGuzal Otamukhamedova, Odiljon E. ZIYADULLAYEV, Abduvahob IKRAMOV, S.I Tirkasheva
JurnalKimyo va kimyo texnologiyasi
NashriyotТошкент кимё-технология институти
ISSN1992-9498, 2181-1121
Nashr sanasi2024-05-03
Jild2024
Son1
TilIngliz
Ilmiy sohaKimyo
DOI10.70189/1992-9498.1549
Indeksga qo‘shilgan2026-09-02

DOI: 10.70189/1992-9498.1549 · Maqolaning asl sahifasi

Ilmiy soha

Kimyo

Iqtibos keltirish

APAGuzal Otamukhamedova, Odiljon E. ZIYADULLAYEV, Abduvahob IKRAMOV, & S.I Tirkasheva (2024). SYNTHESIS OF INTERNAL ACETYLENE ALCOHOLS BASED ON THE SONOGASHIRA REACTION OF TERMINAL ACETYLENE ALCOHOLS AND BENZOLCHLORIDE. Kimyo va kimyo texnologiyasi, 2024(1). https://doi.org/10.70189/1992-9498.1549
GOST (OAK)Guzal Otamukhamedova va b. SYNTHESIS OF INTERNAL ACETYLENE ALCOHOLS BASED ON THE SONOGASHIRA REACTION OF TERMINAL ACETYLENE ALCOHOLS AND BENZOLCHLORIDE // Kimyo va kimyo texnologiyasi. – 2024. – T. 2024, № 1. – DOI: 10.70189/1992-9498.1549.
MLAGuzal Otamukhamedova, Odiljon E. ZIYADULLAYEV, Abduvahob IKRAMOV, and S.I Tirkasheva. “SYNTHESIS OF INTERNAL ACETYLENE ALCOHOLS BASED ON THE SONOGASHIRA REACTION OF TERMINAL ACETYLENE ALCOHOLS AND BENZOLCHLORIDE.” Kimyo va kimyo texnologiyasi, 2024(1), 2024. https://doi.org/10.70189/1992-9498.1549
ChicagoGuzal Otamukhamedova, Odiljon E. ZIYADULLAYEV, Abduvahob IKRAMOV, and S.I Tirkasheva. “SYNTHESIS OF INTERNAL ACETYLENE ALCOHOLS BASED ON THE SONOGASHIRA REACTION OF TERMINAL ACETYLENE ALCOHOLS AND BENZOLCHLORIDE.” Kimyo va kimyo texnologiyasi, 2024(1) (2024). https://doi.org/10.70189/1992-9498.1549
HarvardGuzal Otamukhamedova, Odiljon E. ZIYADULLAYEV, Abduvahob IKRAMOV, and S.I Tirkasheva (2024) ‘SYNTHESIS OF INTERNAL ACETYLENE ALCOHOLS BASED ON THE SONOGASHIRA REACTION OF TERMINAL ACETYLENE ALCOHOLS AND BENZOLCHLORIDE’, Kimyo va kimyo texnologiyasi, 2024(1). https://doi.org/10.70189/1992-9498.1549
BibTeX
@article{guzalotamukhamedova2024,
  title = {SYNTHESIS OF INTERNAL ACETYLENE ALCOHOLS BASED ON THE SONOGASHIRA REACTION OF TERMINAL ACETYLENE ALCOHOLS AND BENZOLCHLORIDE},
  author = {Guzal Otamukhamedova and Odiljon E. ZIYADULLAYEV and Abduvahob IKRAMOV and S.I Tirkasheva},
  journal = {Kimyo va kimyo texnologiyasi},
  year = {2024},
  volume = {2024},
  number = {1},
  doi = {10.70189/1992-9498.1549},
  url = {https://doi.org/10.70189/1992-9498.1549}
}

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