Thermochemical dissolution enthalpy of metalloporphyrins in anhydrous solutions

Sayitova, Nodira Normurodqizi, Tangyarikov, Normurod Sayitovich, Сайитова, Нодира Нормуродкизи, Тангяриков, Нормурод Сайитович, Sayitova, Nodira Normurodkizi, Tangyarikov, Normurod Sayitovich

Саноатда рақамли технологиялар · 2026-yil

Annotatsiya

The article presents a thermochemical study of the dissolution and solvation of chlorophyll (a), its ligand, and its metal analogues containing Cu(II), Ni(II), Co(II), Zn(II), Cd(II), Fe(III), and Mn(III) in anhydrous organic solvents of different chemical nature. Calorimetric measurements were carried out at 298.15 K in inert aprotic solvents, including CCl₄, C₆H₆, and C₆H₅NO₂, the proton-donor solvent CHCl₃, and proton-acceptor solvents such as DMF, pyridine, and piperidine. Standard dissolution enthalpies of the investigated compounds were determined. The experimental results showed that, within the investigated concentration range, the dissolution enthalpy is essentially independent of porphyrin concentration. Benzene was used as a reference solvent to calculate transfer enthalpies to other solvents. Metal complex formation was found to affect both the crystal-lattice energetics and solvation behavior of the porphyrin macrocycles. Chloroform exhibited particularly strong solvating ability toward chlorophyll ligands and their metal complexes, which was attributed to hydrogen bonding and specific solute–solvent interactions. The obtained data provide a basis for identifying the main thermodynamic regularities governing the solvation of metalloporphyrins in solvents with different donor–acceptor properties.

Maqola ma’lumotlari
MualliflarSayitova, Nodira Normurodqizi, Tangyarikov, Normurod Sayitovich, Сайитова, Нодира Нормуродкизи, Тангяриков, Нормурод Сайитович, Sayitova, Nodira Normurodkizi, Tangyarikov, Normurod Sayitovich
JurnalСаноатда рақамли технологиялар
NashriyotҚарши муҳандислик-иқтисодиёт институти
ISSN3030-3214, 2023-2026
Nashr sanasi2026-10-09
Jild4
Son3-1
TilIngliz
Ilmiy sohaKimyo
DOI10.70769/3030-3214.srt.4.3-1.2026.21
Indeksga qo‘shilgan2026-10-10

DOI: 10.70769/3030-3214.srt.4.3-1.2026.21 · Maqolaning asl sahifasi

Kalit so‘zlar

xloroform, xlorofill, ligand, mis, nikel, rux, kadmiy, kobalt, marganes, temir, uglerod, benzol, protonodonor, piridin, piperidin, kalorimetriya, хлороформ, хлорофилл, лиганд, медь, никель, цинк, кадмий, кобальт, марганец, железо, углерод, бензол, протонодонор, пиридин, пиперидин, калориметрия, chloroform, chlorophyll, ligand, copper, nickel, zinc, cadmium, cobalt, manganese, iron, carbon, benzene, proton donor, pyridine, piperidine, calorimetry

Ilmiy soha

Kimyo

Iqtibos keltirish

APASayitova, Nodira Normurodqizi, Tangyarikov, Normurod Sayitovich, Сайитова, Нодира Нормуродкизи, Тангяриков, Нормурод Сайитович, Sayitova, Nodira Normurodkizi, & Tangyarikov, Normurod Sayitovich (2026). THERMOCHEMICAL DISSOLUTION ENTHALPY OF METALLOPORPHYRINS IN ANHYDROUS SOLUTIONS. Саноатда рақамли технологиялар, 4(3-1). https://doi.org/10.70769/3030-3214.srt.4.3-1.2026.21
GOST (OAK)Sayitova, Nodira Normurodqizi va b. THERMOCHEMICAL DISSOLUTION ENTHALPY OF METALLOPORPHYRINS IN ANHYDROUS SOLUTIONS // Саноатда рақамли технологиялар. – 2026. – T. 4, № 3-1. – DOI: 10.70769/3030-3214.srt.4.3-1.2026.21.
MLASayitova, Nodira Normurodqizi, Tangyarikov, Normurod Sayitovich, Сайитова, Нодира Нормуродкизи, Тангяриков, Нормурод Сайитович, Sayitova, Nodira Normurodkizi, and Tangyarikov, Normurod Sayitovich. “THERMOCHEMICAL DISSOLUTION ENTHALPY OF METALLOPORPHYRINS IN ANHYDROUS SOLUTIONS.” Саноатда рақамли технологиялар, 4(3-1), 2026. https://doi.org/10.70769/3030-3214.srt.4.3-1.2026.21
ChicagoSayitova, Nodira Normurodqizi, Tangyarikov, Normurod Sayitovich, Сайитова, Нодира Нормуродкизи, Тангяриков, Нормурод Сайитович, Sayitova, Nodira Normurodkizi, and Tangyarikov, Normurod Sayitovich. “THERMOCHEMICAL DISSOLUTION ENTHALPY OF METALLOPORPHYRINS IN ANHYDROUS SOLUTIONS.” Саноатда рақамли технологиялар, 4(3-1) (2026). https://doi.org/10.70769/3030-3214.srt.4.3-1.2026.21
HarvardSayitova, Nodira Normurodqizi, Tangyarikov, Normurod Sayitovich, Сайитова, Нодира Нормуродкизи, Тангяриков, Нормурод Сайитович, Sayitova, Nodira Normurodkizi, and Tangyarikov, Normurod Sayitovich (2026) ‘THERMOCHEMICAL DISSOLUTION ENTHALPY OF METALLOPORPHYRINS IN ANHYDROUS SOLUTIONS’, Саноатда рақамли технологиялар, 4(3-1). https://doi.org/10.70769/3030-3214.srt.4.3-1.2026.21
BibTeX
@article{sayitovanodiranormurodqizi2026,
  title = {THERMOCHEMICAL DISSOLUTION ENTHALPY OF METALLOPORPHYRINS IN ANHYDROUS SOLUTIONS},
  author = {Sayitova, Nodira Normurodqizi and Tangyarikov, Normurod Sayitovich and Сайитова, Нодира Нормуродкизи and Тангяриков, Нормурод Сайитович and Sayitova, Nodira Normurodkizi and Tangyarikov, Normurod Sayitovich},
  journal = {Саноатда рақамли технологиялар},
  year = {2026},
  volume = {4},
  number = {3-1},
  doi = {10.70769/3030-3214.srt.4.3-1.2026.21},
  url = {https://doi.org/10.70769/3030-3214.srt.4.3-1.2026.21}
}

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