1-ETINILSIKLOGEKSANOLNING ayrim ketonlar bilan tetrabutilammoniy gidroksid yordamida enantioselektiv alkinillanish asosida atsetilen diollar sintezi

Sarvinoz I. Tirkasheva, Odiljon Ziyadullaev, Abduvahob IKRAMOV, Forxod BURIEV

Kimyo va kimyo texnologiyasi · 2024-yil

Annotatsiya

The purpose of the research is to develop a method of synthesizing new acetylene diols, to determine their structure, physico-chemical properties and to create optimal conditions by studying the effect of various environments on product yield. For the first time, nucleophilic coupling reactions of 1-ethynylcyclohexanol with some ketones - cyclohexanone, acetophenone, para-chloroacetophenone, adamantanone, methylhexylketone and ethyl-n-butyl ketones were studied using the Bu4NOH/DMSO/H2O catalytic system. New acetylene diols – 1-(2-(1-hydro-xycyclohexyl)ethynyl)cyclohexanol (1), 1-(3-hydroxy-3-phenylbut-1-ynyl)cyclohexanol (2), 1-(3-(4-chlorophenyl)-3-hydroxybut-1-ynyl)cyclo-hexanol(3), 1-(2-(1-hydroxyadamantanyl)-ethynyl)cyclohexanol (4), 1-(3-hydroxy-3-methyldec-1-ynyl)cyclohexanol(5) and 1-(3-ethyl-3-hydroxyhept-1-ynyl)cyclohexanol (6) were synthesized in the process. The effects of the catalyst for the synthesis of acetylene diols, the nature of the solvent, the mole ratio of the starting materials, the temperature, and the duration of the reaction were systematically analyzed. The composition, structure and purity of the synthesized acetylene diols were determined by modern physical and chemical research methods.

Maqola ma’lumotlari
MualliflarSarvinoz I. Tirkasheva, Odiljon Ziyadullaev, Abduvahob IKRAMOV, Forxod BURIEV
JurnalKimyo va kimyo texnologiyasi
NashriyotТошкент кимё-технология институти
ISSN1992-9498, 2181-1121
Nashr sanasi2024-03-28
Jild2022
Son3
TilO‘zbek
Ilmiy sohaKimyo
DOI10.70189/1992-9498.1557
Indeksga qo‘shilgan2026-09-02

DOI: 10.70189/1992-9498.1557 · Maqolaning asl sahifasi

Ilmiy soha

Kimyo

Iqtibos keltirish

APASarvinoz I. Tirkasheva, Odiljon Ziyadullaev, Abduvahob IKRAMOV, & Forxod BURIEV (2024). 1-ETINILSIKLOGEKSANOLNING AYRIM KETONLAR BILAN TETRABUTILAMMONIY GIDROKSID YORDAMIDA ENANTIOSELEKTIV ALKINILLANISH ASOSIDA ATSETILEN DIOLLAR SINTEZI. Kimyo va kimyo texnologiyasi, 2022(3). https://doi.org/10.70189/1992-9498.1557
GOST (OAK)Sarvinoz I. Tirkasheva va b. 1-ETINILSIKLOGEKSANOLNING AYRIM KETONLAR BILAN TETRABUTILAMMONIY GIDROKSID YORDAMIDA ENANTIOSELEKTIV ALKINILLANISH ASOSIDA ATSETILEN DIOLLAR SINTEZI // Kimyo va kimyo texnologiyasi. – 2024. – T. 2022, № 3. – DOI: 10.70189/1992-9498.1557.
MLASarvinoz I. Tirkasheva, Odiljon Ziyadullaev, Abduvahob IKRAMOV, and Forxod BURIEV. “1-ETINILSIKLOGEKSANOLNING AYRIM KETONLAR BILAN TETRABUTILAMMONIY GIDROKSID YORDAMIDA ENANTIOSELEKTIV ALKINILLANISH ASOSIDA ATSETILEN DIOLLAR SINTEZI.” Kimyo va kimyo texnologiyasi, 2022(3), 2024. https://doi.org/10.70189/1992-9498.1557
ChicagoSarvinoz I. Tirkasheva, Odiljon Ziyadullaev, Abduvahob IKRAMOV, and Forxod BURIEV. “1-ETINILSIKLOGEKSANOLNING AYRIM KETONLAR BILAN TETRABUTILAMMONIY GIDROKSID YORDAMIDA ENANTIOSELEKTIV ALKINILLANISH ASOSIDA ATSETILEN DIOLLAR SINTEZI.” Kimyo va kimyo texnologiyasi, 2022(3) (2024). https://doi.org/10.70189/1992-9498.1557
HarvardSarvinoz I. Tirkasheva, Odiljon Ziyadullaev, Abduvahob IKRAMOV, and Forxod BURIEV (2024) ‘1-ETINILSIKLOGEKSANOLNING AYRIM KETONLAR BILAN TETRABUTILAMMONIY GIDROKSID YORDAMIDA ENANTIOSELEKTIV ALKINILLANISH ASOSIDA ATSETILEN DIOLLAR SINTEZI’, Kimyo va kimyo texnologiyasi, 2022(3). https://doi.org/10.70189/1992-9498.1557
BibTeX
@article{sarvinozitirkasheva2024,
  title = {1-ETINILSIKLOGEKSANOLNING AYRIM KETONLAR BILAN TETRABUTILAMMONIY GIDROKSID YORDAMIDA ENANTIOSELEKTIV ALKINILLANISH ASOSIDA ATSETILEN DIOLLAR SINTEZI},
  author = {Sarvinoz I. Tirkasheva and Odiljon Ziyadullaev and Abduvahob IKRAMOV and Forxod BURIEV},
  journal = {Kimyo va kimyo texnologiyasi},
  year = {2024},
  volume = {2022},
  number = {3},
  doi = {10.70189/1992-9498.1557},
  url = {https://doi.org/10.70189/1992-9498.1557}
}

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