Structure and properties of complexes formed by 5- PHENYLAMINO-1,3,4-THIADIAZOLE-2-THIONE with ni(ii), co(ii), and cu(ii) salts: identification of coordination bonds and functional groups

Ataniyazov, Otaniyoz Nurullayevich, Yuldoshova, Halima Azamat qizi, Xudoybergan Qo'ziyevich, Polvonov

Қўқон ДПИ. Илмий хабарлар · 2026-yil

Annotatsiya

Mazkur tadqiqotda 5-fenilamino-1,3,4-tiadiazol-2-tion asosidagi Co(II), Ni(II) va Cu(II) tuzlari bilan komplekslarining koordinatsion tuzilishi hamda elektron xossalari infraqizil IQ-Furye va UV–Vis-spektroskopiya usullari yordamida kompleks ravishda o‘rganildi. Tadqiqotning asosiy maqsadi 5-almahsgan amino-1,3,4-tiadiazolning metall ionlari bilan o‘zaro koordinatsion ta’siri, donor markazlarning bog‘lanish tabiati hamda kompleks hosil bo‘lish jarayonida yuzaga keladigan elektron delokalizatsiyasini spektral jihatdan ilmiy asoslashdan iboratdir. Cu(II) kompleksi misolidagi ligand–metall elektron o‘zaro ta’sirining tabiati va zaryad ko‘chishi mexanizmlari UV–Vis-spektral tadqiqotlari asosida aniqladi. Unga ko‘ra 300–330 nm oralig‘ida kuzatilgan intensiv yutilish maksimumlari aromatik fragment va 1,3,4-tiadiazol halqasining π→π* intra-ligand elektron o‘tishlariga mos keladi.

Maqola ma’lumotlari
MualliflarAtaniyazov, Otaniyoz Nurullayevich, Yuldoshova, Halima Azamat qizi, Xudoybergan Qo'ziyevich, Polvonov
JurnalҚўқон ДПИ. Илмий хабарлар
NashriyotҚўқон давлат педагогика институти
ISSN3030-3958
Nashr sanasi2026-09-05
Jild8
Son6
Betlar160-172
TilIngliz
DOI10.70728/a.series.tab.v08.i06.023
Indeksga qo‘shilgan2026-09-06

DOI: 10.70728/a.series.tab.v08.i06.023 · Maqolaning asl sahifasi

Kalit so‘zlar

IQ-Furye spektr, 1, 3, 4-tiadiazol, koordinatsion birikma, d metal, metall kompleksi, N–H bog‘lari, ligand, zaryad ko‘chishi, Laporte-qoidasi.

Iqtibos keltirish

APAAtaniyazov, Otaniyoz Nurullayevich, Yuldoshova, Halima Azamat qizi, & Xudoybergan Qo'ziyevich, Polvonov (2026). STRUCTURE AND PROPERTIES OF COMPLEXES FORMED BY 5- PHENYLAMINO-1,3,4-THIADIAZOLE-2-THIONE WITH NI(II), CO(II), AND CU(II) SALTS: IDENTIFICATION OF COORDINATION BONDS AND FUNCTIONAL GROUPS. Қўқон ДПИ. Илмий хабарлар, 8(6), 160-172. https://doi.org/10.70728/a.series.tab.v08.i06.023
GOST (OAK)Ataniyazov, Otaniyoz Nurullayevich, Yuldoshova, Halima Azamat qizi, Xudoybergan Qo'ziyevich, Polvonov STRUCTURE AND PROPERTIES OF COMPLEXES FORMED BY 5- PHENYLAMINO-1,3,4-THIADIAZOLE-2-THIONE WITH NI(II), CO(II), AND CU(II) SALTS: IDENTIFICATION OF COORDINATION BONDS AND FUNCTIONAL GROUPS // Қўқон ДПИ. Илмий хабарлар. – 2026. – T. 8, № 6. – P. 160-172. – DOI: 10.70728/a.series.tab.v08.i06.023.
MLAAtaniyazov, Otaniyoz Nurullayevich, Yuldoshova, Halima Azamat qizi, and Xudoybergan Qo'ziyevich, Polvonov. “STRUCTURE AND PROPERTIES OF COMPLEXES FORMED BY 5- PHENYLAMINO-1,3,4-THIADIAZOLE-2-THIONE WITH NI(II), CO(II), AND CU(II) SALTS: IDENTIFICATION OF COORDINATION BONDS AND FUNCTIONAL GROUPS.” Қўқон ДПИ. Илмий хабарлар, 8(6), 160-172, 2026. https://doi.org/10.70728/a.series.tab.v08.i06.023
ChicagoAtaniyazov, Otaniyoz Nurullayevich, Yuldoshova, Halima Azamat qizi, and Xudoybergan Qo'ziyevich, Polvonov. “STRUCTURE AND PROPERTIES OF COMPLEXES FORMED BY 5- PHENYLAMINO-1,3,4-THIADIAZOLE-2-THIONE WITH NI(II), CO(II), AND CU(II) SALTS: IDENTIFICATION OF COORDINATION BONDS AND FUNCTIONAL GROUPS.” Қўқон ДПИ. Илмий хабарлар, 8(6), 160-172 (2026). https://doi.org/10.70728/a.series.tab.v08.i06.023
HarvardAtaniyazov, Otaniyoz Nurullayevich, Yuldoshova, Halima Azamat qizi, and Xudoybergan Qo'ziyevich, Polvonov (2026) ‘STRUCTURE AND PROPERTIES OF COMPLEXES FORMED BY 5- PHENYLAMINO-1,3,4-THIADIAZOLE-2-THIONE WITH NI(II), CO(II), AND CU(II) SALTS: IDENTIFICATION OF COORDINATION BONDS AND FUNCTIONAL GROUPS’, Қўқон ДПИ. Илмий хабарлар, 8(6), 160-172. https://doi.org/10.70728/a.series.tab.v08.i06.023
BibTeX
@article{ataniyazovotaniyoznurullayevich2026,
  title = {STRUCTURE AND PROPERTIES OF COMPLEXES FORMED BY 5- PHENYLAMINO-1,3,4-THIADIAZOLE-2-THIONE WITH NI(II), CO(II), AND CU(II) SALTS: IDENTIFICATION OF COORDINATION BONDS AND FUNCTIONAL GROUPS},
  author = {Ataniyazov, Otaniyoz Nurullayevich and Yuldoshova, Halima Azamat qizi and Xudoybergan Qo'ziyevich, Polvonov},
  journal = {Қўқон ДПИ. Илмий хабарлар},
  year = {2026},
  volume = {8},
  number = {6},
  pages = {160-172},
  doi = {10.70728/a.series.tab.v08.i06.023},
  url = {https://doi.org/10.70728/a.series.tab.v08.i06.023}
}

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